COMBUSTION OF ELEMENTAL BORON

Abstract

IT WAS CONFIRMED THAT BF is the species evolved from the surface of a heated B rod exposed to F gas inside a mass spectrometer. Evidence indicated that the rate of formation of BF is only slightly dependent on temperature above 1200 K. Preliminary experiments in a microbalance apparatus show no detectable reaction between a high-purity polycrystalline B rod at ambient temperature and F gas at 1 to 200 micron Hg pressure. However, a B rod heated to about 600 K in an image furnace gives a reaction rate of about 10 to the 16th power molecules/sq cm-sec at a F pressure of 1 micron Hg. This value is subject to an upward revision since it corresponds to approximately total consumption of the F at the flow rates possible with the equipment.

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Document Details

Document Type
Technical Report
Publication Date
Feb 01, 1962
Accession Number
AD0273733

Entities

People

  • Harry P. Woods
  • U. V. Henderson Jr.

Organizations

  • Texaco

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Chemical Reaction Properties
  • Chemical Reactions
  • Combustion
  • Flow Rate
  • Fluorine
  • Heat Shields
  • Intensity
  • Ion Sources
  • Mass
  • Mass Spectrometers
  • Microbalances
  • Molecules
  • Rate Of Consumption
  • Rate Of Formation
  • Spectrometers
  • Surface Reactions
  • United States

Readers

  • Combustion science or combustion engineering.
  • Mathematics or Statistics