CARBONIZATION OF PLASTICS AND REFRACTORY MATERIALS RESEARCH PROGRAM. VOLUME II. REFRACTORY MATERIALS RESEARCH

Abstract

Equilibrium N pressures over the ZrN single phase were measured by deter ining the rate of N effusion from a Knudsen cell. The measurements span a range from 1424 to 2360 K, a range of composition from 13.0 down to 9.79% N by weight and a range of N pressures from 2 x 10 to the -8th power to 3 x 10 to the -5th power atm. These data are presented graphically. Both IR and visible spectra were obtained from matrix isolated species effusion from a Knudsen orifice in a cell containing ThO2. The observed bands are tabulated; the analysis of the spectra are not complete. Results of efforts to measure the resonance line absorption by B atoms over pure B indicated serious interacti n of the B with all container material t us far investigated. The 6 compounds, NbB2, TiB2, ZrB2, TaN, ZrN and HfN, for which emissivities are being measured, have been characterized by chemical analysis, density measurement, crystallographic structure, electron micrographic examination and x-ray diffraction measurements. (Author)

Document Details

Document Type
Technical Report
Publication Date
Mar 31, 1962
Accession Number
AD0274654

Entities

People

  • G.m. Kibler
  • T.f. Lyon
  • V.j. Desantis

Organizations

  • General Electric

Tags

DTIC Thesaurus Topics

  • Chemical Analysis
  • Diffraction
  • Effusion
  • Materials
  • Measurement
  • Plastics
  • Refractory Materials
  • Spectra
  • Visible Spectra
  • X Rays
  • X-Ray Diffraction

Fields of Study

  • Physics

Readers

  • Combustion science or combustion engineering.
  • Spectroscopy.
  • Surface Engineering/Surface Coating Technology.

Technology Areas

  • Microelectronics