VOLATILE FLUORO COMPOUNDS
Abstract
This rept. includes: THE PREPARATION AND PROPERTIES OF VANADIUM TETRAFLUORIDE, by R. G. Cavell and H. C. Clark. Feb 62. THE ADDITIO OF T TRAFLUOROE HYLENE TO SOME ORGANO-TIN COMPOUNDS, by M. A. A. Beg and H. C. Clark. Feb 62. PREPARATION AND PROPERTIES OF VF4: The fluorination of VCl4 by anhydrous HF in CCl3F solution to give pure VF4 is described. The results of density, magnetic susceptibility and crystallographic measurements on VF $ RE REPORTED. The salt K2VF6 was obtained from KF and VF4 in SeF4 solution. VF4 reacts with ammonia and pyridine to give the same products as are obtained from reactions of ammonia and pyridine with VF5. Other reactions of VF4 are reported. ADDITION OF C2F4 TO SOME ORGANIC-TIN COMPOUNDS: The white modification of diphenyl tin was prepared and dissolved in CCl4 containing an equimolar amount of C2F4. After exposing the solution to UV radiation a white cryst lline solid as obtained a d characterized as being (C6V5)2SnC2H4. Reaction of h xamethylditin with C2F4 gave a product characterized as (CH3)3SnC2F4Sn(CH3)3.
Document Details
- Document Type
- Technical Report
- Publication Date
- Feb 01, 1962
- Accession Number
- AD0275103
Entities
People
- H.c. Clark
- M.a.a. Beg
- R.g. Cavell
Organizations
- University of British Columbia