THE DESTRUCTIVE ACTION OF LIGHT ON NITROALKANES

Abstract

Study of the spectra of nitro compounds showed that daylight has a destructive effect on nitroalkanes and their salts in aqueous solutions. Data indicated that the closer the wavelength of the incident light to the absorption maximum of the anion of the nitroalkane, the more intense the decomposition effect. The K salts of dinitromethane, 1,1-dinitroethane, and 1,1-dinitropropane were almost completely decomposed as the wavelength of the incident light approached their absorption maximum. This article suggests that new precautionary measures may be necessary in handling this class of liquid propellants. (Author)

Document Details

Document Type
Technical Report
Publication Date
Apr 23, 1962
Accession Number
AD0276172

Entities

People

  • S.a. Shevelev
  • V.i. Slovetskiy

Organizations

  • Library of Congress

Tags

DTIC Thesaurus Topics

  • Absorption
  • Aqueous Solutions
  • Daylight
  • Decomposition
  • Energetic Materials
  • Liquid Propellants
  • Materials
  • Nitro Compounds
  • Propellants
  • Spectra

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Spectroscopy.
  • Systems Analysis and Design