METAL-POLYELECTROLYTE COMPLEXES X, THE POLY-N-VINYLIMIDAZOLE-ZN (II) COMPLEX
Abstract
METAL-POLYELECTROLYTE COMPLEXES X, THE POLY-NVINYLIMIDAZOLE-ZN (II) COMPLEX: The binding of Zn by poly-N-vinylimidazole in 1M NaNO3 at 0.01 and 0.10 M polymer concentrations showed fourfold coordination. TURBIDOMETRIC STUDY OF THE POLY-N-VINYLIMIDAZOLE-Zn (II) COMPLEX: Results indicated that the polymer chain association occurred during the complex formation, with the metal ion acting as cross-linking agent. CATALYTIC STUDIES OF THE DEHYDRATION OF H2CO3: The Zn(II)-poly-N-vinylimidazole complex gave no additional contribution. The catalytic effect of the poly-N-vinylimidazole was estimated in the order of 100 times that of imidazole.
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 01, 1962
- Accession Number
- AD0276669
Entities
People
- Harry P. Gregor
- K.j. Liu
Organizations
- New York University Tandon School of Engineering