CHEMISTRY OF DECABORANE PHOSPHORUS COMPOUNDS. II. SYNTHESIS AND REACTIONS OF DIPHENYLPHOSPHINODECABORANE
Abstract
Decaboranyl sodium and diphenylchlorophosphine reacted in ether solution to form diphenylphosphinodecaborane (Ph2P-B10H13), the first phosphine substituted decaborane with trivalent phosphorus. B-11 NMR spectral investigation proved the substituent to be at the 6-position. Unlike monomeric phosphinoboranes (R2P-BR2), it is unreactive toward Lewis acids, oxidation and quaternization, but undergoes partial degradation with alcohols to form B9H13-(Ph2PH). Its reactions with amines and phosphines resulting in salts containing the Ph2PB10H12 anion are described. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jul 26, 1962
- Accession Number
- AD0278702
Entities
People
- Hansjuergen Schroeder