RESEARCH ON THE PRODUCTION OF ULTRA-PURE MOLYBDENUM

Abstract

The objective was to design and construct an apparatus capable of producing extremely pure Mo in limited quantities and to produce one pound of such metal. A single, carefully-controlled sublimation of MoCl5 yielded a highly purified product without prior purification or recourse to repeated sublimation. Hydrogen reduction of MoCl5 to metal was attempted at atmospheric pressure; to obtain substantial yields it was necessary to operate reductions at reduced pressure. Tubular deposits of metal were consolidated into bulk form by electron beam melting under high vacuum yielding a very low impurity level of gases. Problems involved in monitoring the purity of these materials and the analytical results are also presented. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jan 15, 1962
Accession Number
AD0282732

Entities

People

  • Mario Badiali
  • Noel W. Kirshenbaum
  • Robert Bakish

Tags

DTIC Thesaurus Topics

  • Barometric Pressure
  • Electron Beam Melting
  • Electron Beams
  • Electrons
  • High Vacuum
  • Hydrogen
  • Impurities
  • Materials
  • Melting
  • Metals
  • Molybdenum
  • Monitoring
  • Production
  • Sublimation
  • Vacuum

Readers

  • Combustion science or combustion engineering.
  • Materials Science and Engineering.
  • Organic Chemistry

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers
  • Directed Energy - Pulsed-Laser Deposition
  • Microelectronics
  • Microelectronics - Graphene