MICROWAVE SPECTRUM AND BARRIER TO INTERNAL ROTATION OF CIS 1-FLUOROPROPYLENE,

Abstract

THE MICROWAVE SPECTRUM OF CIS CH3CH=CHF WAS INVESTIGATED IN THE REGION 8 TO 36 KMC. THE ROTATIONAL CONSTANTS ARE 17,826.09, 5656.57, AND 4406.91 MC. THE VALUE OF THE INERTIAL DEFECT INDICATES A PLANAR STRUCTURE EXCEPT FOR THE TWO CH3 HYDROGEN ATOMS. THE BARRIER TO INTERNAL ROTATION OF THE CH3 GROUP WAS DETERMINED TO BE 1057 Y 50 CAL. FROM THE SPLITTING OF THE GROUND STATE TRANSITIONS. THE DIPOLE MOMENT IS 1.46 DEBYE. THE SHARP LOWERING OF THE BARRIER ON INTRODUCTION OF THE CIS F SUGGESTS A DIRECT NONBONDED INTERACTION OF THE F AND CH3 HYDROGENS

Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1962
Accession Number
AD0284173

Entities

People

  • E. Bright Jr. Wilson
  • Robert A. Beaudet

Organizations

  • Harvard University

Tags

DTIC Thesaurus Topics

  • Atoms
  • Dipole Moments
  • Ground State
  • Hydrogen
  • Microwaves
  • Planar Structures
  • Rotation
  • Spectra
  • Splitting
  • Transitions

Fields of Study

  • Chemistry

Readers

  • Analytical Mechanics
  • Electrochemical Engineering/ Fuel Cell Technologies
  • Plasma Physics / Magnetohydrodynamics