PROPULSION RESEARCH PROGRAM. HYDRIDE AND FLUORIDE INVESTIGATIONS

Abstract

The complex formed between sulfur tetrafluoride and tetramethyl ammonium fluoride has been almost completely characterized. The compound believed to be (CH3)4N plus SF5- is stable to 70 to 100 C and reacts with water, nitrobenzene, formamide, and monomethyl formamide. The flourine nuclear magnetic resonance spectrum of the compound exhibits a single line quite different from that of F- or SF4. The reaction between ferric chloride, phenyl magnesium bromide and hydrogen to form iron hydrides was studied. The products have been separated into at least five separate solid components based on differential solubility in various basic solvents.

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1962
Accession Number
AD0285351

Entities

People

  • B. Siegal
  • L. Shieler
  • P. Breisacher
  • R. Tunder
  • S. G. Gibbins

Organizations

  • The Aerospace Corporation

Tags

Communities of Interest

  • Advanced Electronics
  • Space

DTIC Thesaurus Topics

  • Air Force
  • Amides
  • High Vacuum
  • Hydrogen
  • Iron
  • Magnetic Resonance
  • Mass Spectrometers
  • Measurement
  • Metals
  • Nuclear Magnetic Resonance
  • Radio Frequency
  • Resonance
  • Solubility
  • Solvents
  • Spectra
  • Spectrometers
  • Transition Metals

Fields of Study

  • Chemistry

Readers

  • Analytical Chemistry
  • Organic Chemistry
  • Plasma Physics / Magnetohydrodynamics