SYNTHESIS AND PROPERTIES OF SOME CYANURIC CHLORIDE DERIVATIVES

Abstract

Cyanuric chloride was reacted with several negatively substituted primary alcohols. Completely substituted reaction products were obtained with trifluoroethanol, tribromoethanol, pentaerythritol trinitrate, and pentaerythritol dinitrate. Di- and tri-substituted products were obtained with 2-methyl-2-nitro-1-propanol which has a tertiary nitro group, whereas alcohols with primary and secondary nitro groups did not react. The reaction with the potassium salt of nitroform gave a product which gradually decomposed on standing. The monoperchlorate salt of trihydrazino-s-triazine was obtained, but attempts at the preparation of perchlorate derivatives of aminoazido-s-triazines were unsuccessful. Sensitivity and stability data are reported on some of the products.

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Document Details

Document Type
Technical Report
Publication Date
May 11, 1962
Accession Number
AD0285397

Entities

People

  • A. J. Matuszko
  • M. S. Chang

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Air Force
  • Alcohols
  • Alkanes
  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Cyanides
  • Materials Science
  • Organic Chemistry
  • Potassium Chloride
  • Sodium Azides
  • Sodium Compounds

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry