FUEL CELL CATHODE STRUCTURES AND REACTIONS

Abstract

A correlation of physical characteristics of metallic surfaces with their electrochemical behavior as O cathodes was under aken to gain an understanding of the mode of function of specific metallic electrodes in the low temperature range. Preparation of Ni and Pt electrodes are described. The results of surface characterization, including surface purity and grain size, are presented. The ethods used for preparing plain and doped nickel oxide films on the surfaces of nickel (such as vapor deposition and surface oxidation) are described. The importance of this oxide film as a decisive factor in electrode behavior is explained. The background and techniques used in obtaining gas adsorption isotherms are given. The theory behind the studies of electrode polarization, charging curves, and double lay r capacitance is given, followed by the data obtained in measurement of these functions for Ni, Ni , and Pt electrodes. Correlations provide a basis for understanding the factors operative in high performance, low temperature fuel cell cathodes. (Author)

Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1962
Accession Number
AD0286698

Entities

People

  • A. Ehud Levy-pascal
  • William A. Cannon

Organizations

  • Douglas

Tags

DTIC Thesaurus Topics

  • Cells
  • Electrodes
  • Films
  • Fuel Cells
  • Grain Size
  • Isotherms
  • Low Temperature
  • Oxide Films
  • Oxides
  • Vapor Deposition

Readers

  • Electrochemical Surface Science
  • Materials Science and Engineering.
  • Powder metallurgy of Titanium alloys.

Technology Areas

  • Biotechnology