DETERMINATION OF HAZE AND INSOLUBLE RESIDUE AFTER ACETYLATION OF WOODPULP

Abstract

A convenient and rapid procedure is described for determining the haze-foming tendency of woodpulp after acetylation and the amount of insoluble residue in the acetate solution. The method prescribes (1) a pretreatment that involves steeping the sample in water if it is air-dry, followed by steeping t in 85% acetic acid t room temperature, (2) displacement of the dilute acetic acid with glacial acetic acid, () acetylation with a mixture of glacial ACETICACID, ACETIC ANHYRIDE, AND SULFURIC ACID CATALYST, AND (4) measurement of haze and insoluble residue in the acetate solution before and after centrifuging. Approximately 5 hours are required for acetylation and measurement of haze. For a commercial softwood sulfite plp of acetylating grade, the initial haze was 1.6 to 3.0% and the insoluble residue was 0.13 to 0. 32%; after centrifuging, the haze was 1.6 to 2.0%.

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Document Details

Document Type
Technical Report
Publication Date
Nov 01, 1962
Accession Number
AD0290717

Entities

People

  • F. A. Simmonds

Organizations

  • Forest Products Laboratory

Tags

Communities of Interest

  • Ground and Sea Platforms

DTIC Thesaurus Topics

  • Acetates
  • Acetic Acid
  • Acetylation
  • Acids
  • Anhydrides
  • Boiling Point
  • Catalysts
  • Cells
  • Cellulose
  • Cellulose Acetates
  • Chemical Synthesis
  • Chemistry
  • Cold Water
  • Government Procurement
  • Hot Water
  • Materials
  • Water

Readers

  • Analytical Chemistry
  • Forest Ecology
  • Spectroscopy.