SYNTHESIS OF ORGANOSILICON MONOMERS WITH NITRILE GROUPS

Abstract

For the purpose of obtaining new organosilicon monomers with nitrile groups, the addition of Cl3SiH to cyclohexene-3-carbonitrile was studied. The best results in the addition of trichlorosilane to cyclohexenecarbonitrile were obtained when tertiary butyl peroxide was used as a catalyst. The use of IR spectra for the identification of the addition products did not give positive results. Considerable amounts (up to 60-90%) of SiCl4 formed attests to the disproportionation of HSiCl3 under the action of nitrogen-containing compounds present in the reaction mixture. (Author)

Document Details

Document Type
Technical Report
Publication Date
Oct 26, 1962
Accession Number
AD0292663

Entities

People

  • A.d. Petrov
  • Ye. P. Zakharov

Organizations

  • National Air and Space Intelligence Center

Tags

DTIC Thesaurus Topics

  • Catalysts
  • Chemical Compounds
  • Cyclic Hydrocarbons
  • Cyclohexenes
  • Disproportionation
  • Hydrocarbons
  • Identification
  • Nitrogen
  • Organic Compounds
  • Peroxides
  • Spectra

Readers

  • Combustion science or combustion engineering.
  • Polymer Science and Technology
  • Theoretical Analysis.