THE REACTION OF ALLYLTRICHLOROSILANE WITH GLYCIDYL METHACRYLATE

Abstract

The reaction of epoxides with chlorosilanes have been applied to the synthesis of several polymers. In particular, allyltrichlorosilane reacts with three moles of glycidyl methacrylate to form a monmer wich can be converted to a clear, hard polymer. Chemical and infrared evidence is presented for the manner in which the monomer is formed, its structure, and the manner in which it polymerizes. Electrical volume resistivity measurements were used to find the optimum polymerization conditions and to ascertain qualitatively the degree of crosslinking. (Author-PL).

Document Details

Document Type
Technical Report
Publication Date
Dec 27, 1962
Accession Number
AD0299308

Entities

People

  • Robert M. Brown

Organizations

  • Naval Ordnance Laboratory

Tags

DTIC Thesaurus Topics

  • Acrylates
  • Acyclic Acids
  • Carboxylic Acids
  • Chemical Compounds
  • Measurement
  • Methacrylates
  • Polymerization

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Polymer Science and Technology