Difluoramine Chemistry
Abstract
The study of the chemistry of the organic NF2 group was continued. Deuterium exchange studies established that the alpha-H atoms in secondary aliphatic bis-difluoramines are not acidic and are not sufficiently labile to permit base catalyzed addition on the alpha-carbon atom. The unexpected redox reaction between organic bis-difluoramines and permanganate ion was investigated further. Extensive fragmentation of the organic molecules resulted. An acid catalyzed reaction was also observed with hydrogen peroxide. Two model gem compounds, 1,1-bis(difluoramino)cyclohexane and 2,2-bis(difluoramino) propane, were prepared. An interesting correlation of mass spectral fragmentation patterns was obtained between the latter compound and the olefin-N2F4 adducts.
Document Details
- Document Type
- Technical Report
- Publication Date
- Sep 01, 1961
- Accession Number
- AD0326201
Entities
People
- A. Kotloby
- C. Vogel
- D. Grafstein
- D. Yee
- R. Storey