Research in Fluoro-Nitro Compounds
Abstract
5,5-Dinitro-2,2-bis(difluoramino)hexane and 5,5,5-trinitro-2,2- bis(difluoramino)pentane were prepared from the corresponding nitroketones and difluoramine in H2SO4 under pressure. t-Butyldifluoramine was absorbed by H2SO4 without gas evolution. Hydrolysis of the intermediate gave acetone quantitatively. HNF2 was added for the first time to a simple linear olefin (1-octene). Ethyl N-fluorocarbamate reacted with aliphatic aldehydes in the presence of a trace of HCl to give the corresponding monoadducts and diadducts. Adducts of ethyl N-fluorocarbamate and olefins were also prepared in the presence of mineral acids. Aqueous fluorination of the butyraldehyde-ethyl N-fluorocarbamate diadduct resulted in the replacement of one of the carbethoxy groups by F.
Document Details
- Document Type
- Technical Report
- Publication Date
- Mar 01, 1962
- Accession Number
- AD0329097
Entities
People
- K. Baum
- V. Grakauskas
Organizations
- Aerojet Rocketdyne Holdings