DISSOCIATION OF POLYNITROMETHYLCARBINOLS. II. DISSOCIATION OF SOME 2-SUBSTITUTED DERIVATIVES OF 2,2-DINITROETHANOL IN AQUEOUS SOLUTION

Abstract

The dissociation of the carbinol Z(NO2)2CCH2OH, according to the equation, Z(NO2)2CCH2OH + OH(-) == Z(NO2)2C + CH2(OH)2, was shown to be an equilibrium in water for six Z(F, CH3, Cl, Br, NO2CN). The equilibrium constant, K, for this reaction was measured at 10 and 25, and used to calculate delta H and delta S for the carbinol dissociation. Measurements of the ionization constant for Z(NO2)2CH were also made for water at 10 and 25. (Author)

Document Details

Document Type
Technical Report
Publication Date
Mar 13, 1964
Accession Number
AD0350193

Entities

People

  • Thomas N. Hall

Organizations

  • Naval Ordnance Laboratory

Tags

DTIC Thesaurus Topics

  • Aqueous Solutions
  • Carbinols
  • Chemical Compounds
  • Chemical Reaction Properties
  • Chemical Reactions
  • Dissociation
  • Equations
  • Ionization
  • Mathematics
  • Measurement
  • Water

Fields of Study

  • Chemistry

Readers

  • Analytical Chemistry
  • Molecular Photonics/Laser Physics