ADVANCED OXIDIZER RESEARCH
Abstract
Neither perfluorogaunidine nor HNCO could be induced to add to the double bonds of 1,2-bis (fluorimino)cyclohexane. Photolysis of 1,4-bis (fluorimino)cyclohexene-2 in cyclohexane solution resulted in rapid reaction, accompanied by darkening and precipitation. The acidcatalyzed reaction of n- heptanal with NF2 was studied and conditions favoring formation of gem-bis(NF2) or the symmetrical ether were defined. Dehydrofluorination of 1,1-bis(NF2) heptane did not yield the corresponding trifluoroamidine in a straightforward manner. The synthesis and gas chromatographic purification of aliphatic difluoramines are reported for evaluation of the relationship between structure and sensitivity.
Document Details
- Document Type
- Technical Report
- Publication Date
- Jun 30, 1964
- Accession Number
- AD0352713
Entities
People
- Donald D. Perry