RESEARCH IN FLUORO-NITRO COMPOUNDS

Abstract

The reaction of 1-nitro-1-nitrosocyclohexane with NF2 in the presence of the BF3 complex of H3PO4 gave nitrocyclohexane and 1-nitro-1-(fluoroazoxy) cyclohexane. The uncatalyzed reaction of alkyl nitrites with NF2 gave the corresponding alcohols. 1-Chloro-1-nitrobutane was nitrosated, and the unstable product was treated with NF2 in fuming H2SO4 to give 1-chloro-1,1-bis(NF2) butane. Evidence was obtained showing that N-fluoroformamide is produced in the direct fluorination of formamide.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1964
Accession Number
AD0353118

Entities

People

  • J. M. Cavallo
  • K. Baum
  • M. P. Mascari
  • V. Grakauskas

Organizations

  • Aerojet Rocketdyne Holdings

Tags

Communities of Interest

  • Energy and Power Technologies
  • Human Systems
  • Weapons Technologies

DTIC Thesaurus Topics

  • Acids
  • Alkanes
  • Amides
  • Amines
  • Chemical Products
  • Chemical Shifts
  • Chlorides
  • Contracts
  • Gas Chromatography
  • Hydrocarbons
  • Infrared Spectra
  • Materials
  • Organic Compounds
  • Phosphoric Acids
  • Sodium Compounds
  • Sodium Hydroxide
  • United States

Fields of Study

  • Chemistry

Readers

  • Analytical Chemistry
  • Organic Chemistry