RESEARCH IN FLUORO-NITRO COMPOUNDS

Abstract

The reactions of 1-difluoraminobutane and 2-difluoraminobutane with concentrated sulfuric acid gave the monovalent ions, CH2=NF-CH2-CH2CH3 and CH3CH=NFCH2CH3, respectively. A 1:1 adduct of isoprene and difluoramine was obtained, using the boron trifluoride complex of phosphoric acid as catalyst. The reaction of 2,2-bis(difluoramino)octane with sulfuric acid, with vigorous agitation, gave 2-octanone. The reaction of alpha, alpha-dibromo-alpha- difluoraminotoluene with sodium 2-propanenitronate gave alphabromo-alpha- fluoriminotoluene. The fluorination of ethyl methoxycarbamate gave N,N'- dimethoxyN,N'-dicarbethoxyhydrazine instead of the expected NF derivatives. Methyl alpha-difluoraminobutyrate was synthesized, and contrary to the reported difluoraminoacetate, the compound does not undergo dehydrofluorination on storage. An NF-containing compound was obtained in the fluorination of 2,4,6- trichloroaniline.

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Document Details

Document Type
Technical Report
Publication Date
May 01, 1965
Accession Number
AD0360916

Entities

People

  • A. H. Remanick
  • H. Marcus
  • H. Nelson
  • K. Baum
  • O. S. Schaeffler
  • V. Grakauskas

Organizations

  • Aerojet Rocketdyne Holdings

Tags

Communities of Interest

  • Human Systems
  • Weapons Technologies

DTIC Thesaurus Topics

  • Acids
  • Alcohols
  • Chlorides
  • Contracts
  • Corporations
  • Diffraction
  • Fluorination
  • Fluorine
  • Infrared Spectra
  • Liquid Phases
  • Materials
  • Organic Compounds
  • Perchlorates
  • Phase
  • Spectra
  • United States
  • X Rays

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry