RESEARCH IN FLUORO-NITRO COMPOUNDS.

Abstract

Reactions of aryldiazonium salts with difluoramine were studied with the objective of synthesizing aryldifluoramines. The products of these reactions, however, were fluoroaryl azides or aromatic hydrocarbons, depending on the nature of the benzenediazonium salts. Phenyl azide and isopropyl fluoroformate were obtained in the reaction between isopropyl N-fluorocarbamate and benzenediazonium fluoborate. Analogous reactions were encountered with o-, m-, and p-nitrobenzenediazonium fluoborates. Fluorammonium perchlorate (SAP) was obtained quantitatively in the reaction between isopropyl N-fluorocarbamate and anhydrous perchloric acid. A process based on this reaction was developed, and SAP is now being produced in lots of 70 to 140 g. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1966
Accession Number
AD0376295

Entities

People

  • K. Baum
  • L. A. Maucieri
  • V. Grakauskas

Organizations

  • Aerojet Rocketdyne Holdings

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Acids
  • Aromatic Hydrocarbons
  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Contracts
  • Corporations
  • Cyclic Hydrocarbons
  • Government Procurement
  • Governments
  • Hydrocarbons
  • Infrared Spectra
  • Materials
  • Organic Chemistry
  • Perchloric Acid
  • Sodium Compounds
  • United States

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry