ADVANCED OXIDIZER RESEARCH.

Abstract

N2F3AsF6 was observed to be compatible with the perchlorates; KClO4, NH4ClO4, and (CH3)4NClO4, in the solid state. Metathesis with perchlorates in liquid sulfur dioxide at -50 C was unsuccessful because of reaction of N2F3AsF6 with the solvent to produce NOAsF6. N2F3AsF6 reacts rapidly with the strongly acidic solvent, HSO3F. Fluorination of Cl2NF over CsF at low temperatures gave only known compounds. The attempted preparation and in situ fluorination of CF3OCl was unsuccessful. The fluorination of a purple Cl2-O2AsF6 adduct at -80 C produced an unidentified volatile product, in addition to ClO3F and oxides of chlorine. No stable adducts could be isolated in the reactions of C-NF2 and C=NF compounds with AsF5 or BF3. Attempts to synthesize N-fluorooxaziranes from ketofluorimines were unsuccessful. CF3OF does not form adducts with AsF5 or BF3. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Jul 31, 1966
Accession Number
AD0376350

Entities

People

  • Archie R. Young Ii
  • Joseph Dvorak

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Abstracts
  • Chemical Synthesis
  • Chemistry
  • Chlorine
  • Contracts
  • Dielectric Gases
  • Fluorination
  • Fluorine
  • Halocarbon Plastics
  • Halogens
  • Infrared Spectra
  • Military Research
  • National Security
  • Security
  • Solid Rocket Oxidizers
  • Spectra
  • Stainless Steel

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry