ADVANCED OXIDIZER RESEARCH

Abstract

The existence of trifluorodiazyl ions in BrF5 and in IF5 was established by F19 n.m.r. and infrared analyses. Solutions of N2F3AsF6 in IF5 treated with perchlorates showed absorptions of N2F3(+) and ClO4(-) in the infrared. Attempts to isolate trifluorodiazyl perchlorate from solution were not successful. An attempt to prepare N3F5 by reaction of N2F3AsF6 with triphenyl fluoroaminomethane at -70 degrees resulted in the formation of N2F4 and trans-N2F2. Attempts to prepare new interhalogen oxides by the fluorination of Cl2.O2AsF6 and NOCl.O2AsF6 were unsuccessful.

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Document Details

Document Type
Technical Report
Publication Date
Jan 31, 1967
Accession Number
AD0379107

Entities

People

  • Archie R. Young Ii
  • Joseph Dvorak

Tags

DTIC Thesaurus Topics

  • Absorption
  • Classification
  • Contractors
  • Fluorination
  • Military Research
  • Perchlorates

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry