IMPROVEMENT OF SENSITIVITY OF LMH-1 PROPELLANTS

Abstract

Thiokol's program to define the cause of LMH-1 propellant sensitivity and, in turn, to decrease the sensitivity characteristics of these propellants was divided into two phases: Phase I - Sensitivity Definition, and Phase II - Sensitivity Improvement. Factors affecting the sensitivity of both cured and uncured LMH-1 propellant have been investigated and defined. Studies which were conducted with regard to sensitivity definition indicated that both LMH-1 and ammonium perchlorate, separately, are insensitive to both impact and friction. The friction sensitivity of LMH-1 propellants is due to the relative ease of reaction of LMH-1 with oxidizer, and that to desensitize these propellants, contact between the two must be prevented or limited. Various methods of sensitivity improvement were examined. Some of these were surface treatments and coatings, binder solid bond studies, pasting techniques, and interrelationships between propellant variables. The friction sensitivity of the LMH-1 formulation tests varied from 1200 to 6000 rpm. The application of techniques to physically limit the contact of fuel to oxidizer, or to reduce the friction produced by the contact were responsible for these large decreases of sensitivity. These results were far beyond the established goals of the program. Impact sensitivity of propellants was found to be significantly affected by changes in ingredient particle size of solid ingredients. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1967
Accession Number
AD0380744

Entities

People

  • E. Gene Goree
  • Marion R. Priest Jr

Tags

DTIC Thesaurus Topics

  • Air Force
  • Ammonium Perchlorate
  • Chlorides
  • Chlorine Compounds
  • Composite Propellants
  • Energetic Materials
  • Friction
  • High Energy Propellants
  • Materials
  • Materials Laboratories
  • Materials Testing
  • Particle Size
  • Perchlorates
  • Propellants
  • Rdx
  • Silicon Carbide
  • Solid Rocket Oxidizers

Fields of Study

  • Physics

Readers

  • Control Systems Engineering.
  • Organic Chemistry
  • Tribology (the study of the boundary interaction between sliding surfaces, lubrication, wear and friction).