KINETICS OF DECOMPOSITION OF SOLID OXIDIZERS.

Abstract

Studies on the structural characterization of P-BEP and its unsaturated percursor PEP indicated that the structures of these compounds deviate from that previously proposed. This is based upon fluorine-19 and hydrogen-1 nmr analysis of the as received samples. Thermal studies in a static reactor indicate that P-BEP spatters during pyrolysis. Quantitative analysis of the product gases from the 160 C. pyrolysis indicates that hydrogen fluoride is one of the most abundant products. Mass spectrometric study of the pyrolytic decomposition has shown that spattering with gas evolution occurs at 50 C. to 55 C. Hydrogen fluoride is also the largest fragment observed at this low temperature. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Apr 15, 1967
Accession Number
AD0381407

Entities

People

  • Thomas E. Dergazarian

Tags

DTIC Thesaurus Topics

  • Absorption
  • Abstracts
  • Air Force
  • Alkenes
  • Anhydrides
  • Chlorides
  • Contracts
  • Fluorine
  • Hydrogen
  • Kinetics
  • Mass Spectra
  • Materials
  • Molecular Weight
  • Spectra
  • Spectroscopy
  • Structural Analysis
  • Thermal Analysis

Readers

  • Combustion science or combustion engineering.
  • Molecular and Cellular Biochemistry