The Detection of Toxic Vapours in the Atmosphere by Infrared Spectrophotometry. 4, Atmospheric Samples from H. M. Ships

Abstract

Samples of air taken aboard selected types of H.M. ships have been analysed by infrared spectrophotometry using long optical-path gas cells. Nine gases, acetylene, carbon dioxide, carbon monoxide, carbonyl sulphide, ethylene, Freon 12, hydrocarbons, hydrogen cyanide, and methane were detected at concentrations high enough to be determined quantitatively and traces of several other gases were also identified. In addition, there were a number of absorption bands, in the spectra obtained from some samples, which could not be identified unequivocally. In surface vessels, under 'shut-down' conditions, and in a submarine during submersion, the concentrations of some contaminants built up to a high level. Any chemical entering the citadel was dispersed to all parts of the air circulation system. It is concluded that no interference with detection devices at present under investigation is likely from any of the compounds detected at the concentrations measured.

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1969
Accession Number
AD0399332

Entities

People

  • L. C. Thomas
  • P. A. Hollingdale-smith

Tags

Communities of Interest

  • Ground and Sea Platforms
  • Weapons Technologies

DTIC Thesaurus Topics

  • Absorption
  • Air Pollution
  • Alcohols
  • Alkenes
  • Carbon Dioxide
  • Carbon Monoxide
  • Chemical Synthesis
  • Chemistry
  • Detection
  • Dielectric Gases
  • Environmental Pollutants
  • Formic Acid
  • Hydrocarbons
  • Methanols
  • Naval Vessels
  • Naval Warfare
  • Organic Chemistry

Fields of Study

  • Environmental science

Readers

  • Naval Architecture and Marine Engineering.
  • Organic Chemistry
  • Thermal Physics or Thermal Science.