A New Process for the Manufacture of Styphnic Acid

Abstract

A new process has been developed for the manufacture of styphnic acid (2,4,6-trinitroresorcinol). Resorcinol is treated with dilute nitric acid and sodium nitrite to give 2,4-dinitrosoresorcinol, and the latter is pumped as a slurry into hot concentrated nitric acid, in which it undergoes oxidation and nitration to yield styphnic acid (90 per cent). The process has been evaluated in collaboration with ROF, Bridgwater, and appears to be more convenient and economical than the conventional sulphonation/nitration method.

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Document Details

Document Type
Technical Report
Publication Date
Jun 13, 1969
Accession Number
AD0399653

Entities

People

  • D. A. Salter
  • R. J. Simkins

Tags

Communities of Interest

  • Ground and Sea Platforms

DTIC Thesaurus Topics

  • Acids
  • Crystals
  • Dermatologic Agents
  • Digestive System Processes
  • Government (Foreign)
  • Governments
  • Materials
  • Melting
  • Melting Point
  • Mixtures
  • Nitration
  • Nitric Acid
  • Nitrogen Compounds
  • Oxidation
  • Sodium Compounds
  • Styphnic Acids
  • Technical Information Centers

Fields of Study

  • Chemistry

Readers

  • Agricultural Chemistry/Soil Science
  • Analytical Chemistry
  • Organic Chemistry