SOME REACTIONS OF DIALKYLAMINOBORONS
Abstract
Consideration of the established hydroboration, chloroboration and phenylboration reactions prompted attempts to extend this concept to aminoboration. Although addition to ethylenic bonds did not occur, it was found that addition to organic isocyanates and isothiocyanates readily occurred to give the expected boroureas. When applied to boron isocyanates and isothio cyanates however, disproportionations involving the boron substituents prevailed in good yield. Ultimately by such disproportions examples of the novel C6H5B(NR2)NC O(S) series of compounds were prepared.
Document Details
- Document Type
- Technical Report
- Publication Date
- May 08, 1963
- Accession Number
- AD0403376
Entities
People
- H. D. Smith
- T. L. Heying