IMPROVEMENT OF THERMAL STABILITY OF TEXTILE FIBERS

Abstract

Improvements on, or alternatives to, the acrylonitrile melt retarding process were sought by three different approaches. First, trying to crosslink with halo-phosphorous compounds, and thus to combine melt and flame retardation holds excellent promise for an alternative process of meltproofing, but has not been found practical for flameproofing. Second, coating by inter facial polymerization. Time was not sufficient to elaborate all the many angles of this group of reactions. It was established that the basic method can be applied on a laboratory scale and does lead to meltproofing. An elaboration of this approach with a view to achieving simulta neous flame retardation is highly indicated. Finally, reactivating melt-retarding coatings for the anchorage of flameretarding agents. Promising leads uncovered were the copolymerization of acrylonitrile with methacryloylchloride, though the subsequent steps of anchoring a suitable chemical to the active acid chloride site has not been worked out.

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1962
Accession Number
AD0405568

Entities

People

  • F. R. Eirich
  • P. G. Assarsson
  • W. M. Lee

Organizations

  • New York University Tandon School of Engineering

Tags

Communities of Interest

  • C4I

DTIC Thesaurus Topics

  • Acids
  • Alcohols
  • Alkenes
  • Anhydrides
  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Contracts
  • Ethylene Glycol
  • Films
  • Glass Transition Temperature
  • Materials
  • Organic Chemistry
  • Polymers
  • Side Reactions
  • Thermal Stability
  • Transition Temperature

Readers

  • Materials Science
  • Polymer Science and Technology
  • Theoretical Analysis.