ACIDODIETHYLENETRIAMINEGOLD (III) COMPLEXES: PREPARATION, SOLUTION CHEMISTRY AND ELECTRONIC STRUCTURE

Abstract

The preparation of acidodiethylenetriaminegold (III) salts with the general formula (Au(dien)X) X2 (dien NH2C2H4NHC2H4NH2 and X Cl(-), Br(-) is reported. The complexes are acids in aqueous solution, ionizing a proton from one of the amine nitrogen atoms. The resulting con jugate bases, (Au(dien-H)X) X (dien-H) dien less one proton and X Cl(-), Br(-), were isolated. Equilibrium constants for (N-H) ionization and for the hydrolysis are given. Electronic spectra of the (Au(dien)X)(2) and (Au(dien-H)X)() complexes are assigned using a molecular orbital level classification.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1962
Accession Number
AD0407679

Entities

People

  • A. J. Poe
  • Clarita Nolting
  • Fred Basolo
  • Harry B. Gray
  • William H. Baddley

Organizations

  • Northwestern University

Tags

Communities of Interest

  • Advanced Electronics
  • C4I

DTIC Thesaurus Topics

  • Absorption
  • Absorption Spectra
  • Air Force
  • Aqueous Solutions
  • Charge Transfer
  • Chemical Reaction Properties
  • Chemical Synthesis
  • Chemistry
  • Cold Water
  • Energy
  • Energy Bands
  • Energy Levels
  • Ligands
  • Materials
  • Mixing
  • Mixtures
  • Organic Chemistry

Fields of Study

  • Chemistry

Readers

  • Analytical Chemistry
  • Quantum Chemistry

Technology Areas

  • Microelectronics
  • Space