Studies in Ion Solvation in Mixed Solvents

Abstract

The objectives of the work were to study the behaviour of the pairs of ions: (1) H(), Cl(-); H(), Br(-); H(), I(-); (2) H() OH(-) Li(), Cl(-); Na() , Cl(-); K(), Cl(-) in methanol water and dioxan-water mixtures by two techniques. (3) E.m.f. measurements on the appropriate chemical cells to deduce the free energy changes and changes in related thermodynamic quantities associated with the transfer of the various pairs of ions from water to the mixed solvent systems. (4) Mesurements, either direct or indirect, of the so-called Washburn numbers of the electrolytes in these systems.

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Document Details

Document Type
Technical Report
Publication Date
Oct 31, 1962
Accession Number
AD0410071

Entities

People

  • D. Feakins

Organizations

  • Birkbeck, University of London

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Accuracy
  • Alcohols
  • Alkali Metals
  • Aqueous Solutions
  • Chemistry
  • Electrolytes
  • Equations
  • Free Energy
  • Halogens
  • Hydrochloric Acid
  • Hydrogen Electrodes
  • Hydroxides
  • Materials
  • Measurement
  • Potassium
  • Protons
  • Silver Halides

Fields of Study

  • Chemistry

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Molecular Photonics/Laser Physics