DETERMINATION OF SPECTROSCOPIC AND THERMODYNAMIC CONSTANTS FOR A SYSTEM OF 1:1 AND 2:1 COMPLEX EQUILIBRIUM REACTIONS,

Abstract

A method of determining the formation constants and the molar absorbancy indices of several complex systems is described. It is shown that observed variations in the apparent formation constant with wavelength or concentration (based on the assumption of only 1:1 interactions) may be attributable to consecutive or simultaneous formation of higher order complexes. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1963
Accession Number
AD0413760

Entities

People

  • Neil B. Jurinski

Organizations

  • University of Mississippi

Tags

DTIC Thesaurus Topics

  • Complex Systems

Readers

  • Analytical Chemistry
  • Theoretical Analysis.