(No title).

Abstract

This report is a summary of the work carried out during the final year of the contract and a brief resume of the results of the complex contract. EExperimental and theoretical studies of both ground state properties and reactivities of organometallic complexes have been made. Elec tron distribution effects in substituted tri carbonylarene-chromiums have been explained by molecular-orbtial theory. ''Stable'' pi com plexes were found to undergo most interesting photolysis and produce hitherto unknown eth oxides. Decomposition of stable pi-complexes in acid solutions can also lead to reduction of other organic systems. Unstable pi-complexes can be used as sites for the formation of metal hydrogen bonds with concomitant reduction. (Author)

Document Details

Document Type
Technical Report
Publication Date
Aug 22, 1963
Accession Number
AD0415621

Entities

Organizations

  • University College Dublin

Tags

DTIC Thesaurus Topics

  • Chemical Reactions
  • Chromium
  • Contracts
  • Decomposition
  • Dissociation
  • Elements
  • Ground State
  • Hydrogen
  • Hydrogen Bonds
  • Lysis
  • Metals
  • Photodecomposition
  • Photolysis
  • Reactivities

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry
  • Technical Research and Report Writing.