THE SYNTHESIS OF NEW INORGANIC MOLECULES.
Abstract
A series of triphenylphosphonium salts were pre pared and characterized. It was found that onium structure is best established by means of absorp tion spectroscopy. The formation of a wide variety of donor-acceptor was -3lished, showing that such compounds as TiBr4, SbCl5, MoCl5, SnCl4, etc. could act as acids toward a considerable number of bases. In addition, such compounds as R3AsO and R3PO were shown to be capable of forming weak field complexes with the simple transition metal ions, similar to the classical aquometal ion complexes. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Aug 31, 1963
- Accession Number
- AD0418217
Entities
People
- S.y. Tyree
Organizations
- University of North Carolina at Chapel Hill