THE SYNTHESIS OF UNSATURATED FLUOROCARBONS

Abstract

A study has been made of the reaction of sodium nitrosyl with hexafluorobenzene but no nitroso pentafluorobenzene was formed. Two silanes containing the trifluorovinyl group have been synthesized. One of these, CF2CF(CH2)2Si(CH3)3 has been treated with NOCl but no nitroso compound was formed. Gas-phase additions of NOCl with fluoroolefins has been continued. Trifluoro vinyllithium did not react with hexafluorobenzene to give perfluorostyrene. A study was made of the reaction of perfluoroallyl chloride with mercurous nitrate. Some acryloyl fluoride was obtained but not enough for a practical synthesis. Perfluoroallyl iodide has been coupled to 1,5-perfluorohexadiene via the mercury allyl.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1962
Accession Number
AD0418540

Entities

People

  • David Sayers
  • Frank Pisacane
  • John Savory
  • Paul Tarrant
  • Ward Oliver

Organizations

  • University of Florence

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Alkenes
  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Ethers
  • Fluorine
  • Fluorine Compounds
  • Gas Chromatography
  • Infrared Spectra
  • Materials
  • Nitro Compounds
  • Nitrogen Oxides
  • Nitroso Compounds
  • Organic Chemistry
  • Organic Compounds
  • Spectra

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry