THE SYNTHESIS OF A VOLATILE CADMIUM CHELATE AND THE STUDY OF ITS VAPOR PHASE REACTION WITH HYDROGEN SULFIDE

Abstract

A chemical approach to deposition of thin films or crystals of metal compounds was investigated. It was of interest to determine whether metal chelates would undergo a vapor phase reaction to form the desired products. Reactions to produce materials of importance as semiconductors were of special interest. Two metal derivatives of fluorinated acetylacetone containing cadmium were pd, one ionic in nature and the other covalent. Composition and structure of the two compounds is presented, together with a few of their physical properties. The covalent cadmium chelate was reacted in the vapor phase with hydrogen sulfide. The experiments were conducted at atmospheric pressure and reaction temperatures of 140 to 240 C.

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Document Details

Document Type
Technical Report
Publication Date
May 01, 1963
Accession Number
AD0419017

Entities

People

  • Albert G. Cupka

Organizations

  • Air Force Institute of Technology

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Air Force
  • Cadmium Compounds
  • Calcium Compounds
  • Chelate Compounds
  • Chemical Analysis
  • Chemical Compounds
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Compound Semiconductors
  • Coordination Complexes
  • Hydroxides
  • Inorganic Chemistry
  • Materials
  • Organic Chemistry
  • Organic Compounds
  • Organometallic Compounds

Fields of Study

  • Chemistry

Readers

  • Materials Science and Engineering.
  • Organic Chemistry

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene