ULTRA-FINE PARTICLE SIZE FERROELECTRICS.

Abstract

Studies were directed to the preparation and evaluation of dense, unsupported films of controlled-purity barium titanate with sub-micron crystallite sizes. As a result, it has been possible to obtain films 30 to 60 microns thick, in pieces as large as one inch square, substantially free from pinholes. Although no direct measurement of density was performed, examination of the films with the aid of both the optical and electron microscope, and a consideration of their electrical properties, suggested a high degree of densification. Films thus prepared from high purity BaTiO3 incorporating, for example, 2.5% Ta2O5 and 0.5% SiO2, possessed grain sizes averaging 0.3 microns; the dielectric constant was about 3000 at room temperature, and the temperature variation was similar to the behavior of thick specimens of a similar composition and grain size. Breakdown field was about 55 kV/cm. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jul 15, 1963
Accession Number
AD0420420

Entities

People

  • Jules Magder
  • Robert Lockhart
  • Virgil L. Mcintosh

Organizations

  • University of Chicago

Tags

DTIC Thesaurus Topics

  • Barium
  • Barium Titanates
  • Crystallites
  • Dielectric Permittivity
  • Electrical Properties
  • Electron Microscopes
  • Electrons
  • Grain Size
  • Measurement
  • Microscopes
  • Particle Size
  • Particles
  • Test And Evaluation
  • Titanates

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Powder metallurgy of Titanium alloys.
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene