INTERMOLECULAR FORCES IN CONDENSED PHASES,
Abstract
Band contours have been observed for non-polar molecules in the liquid phase and in solution in non-polar solvents with a spectral slit width of about l rec. cm. A criterion was established for measuring the relative amounts of Lorentzian and Gaussian character to a band. It was found that symmetric bands were Lorentzian and that asymmetry appeared as a consequence of intramolecular effects that could be shown to be present in the vapor phase spectrum. Hydrogen bonding was studied in the mono- and di-hydroxyanthraquinones, by means of infrared spectroscopy, nuclear magnetic resonance, and x-ray diffraction. Infrared spectra were obtained on solutions, solids, and vapors, nuclear magnetic resonance spectra on solutions, x-ray diffraction on a single crystal. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Aug 01, 1963
- Accession Number
- AD0421016
Entities
People
- Robert P. Bauman
Organizations
- New York University Tandon School of Engineering