ELECTRON SPIN RESONANCE (ESR) STUDY OF GAMMA IRRADIATED SOLID ACETONITRILE.

Abstract

The solid phase Cobalt-60 radiolysis of acetonitrile was investigated. Free radicals produced during the exposure to gamma rays were studied with an electron-spin resonance spectrometer and the final products were determined by gas chromatography and mass spectrometry. Predominant products are hydrogen, methane, and succinonitrile. The reaction paths to these products are inferred from, and consistent with, the ESR spectra of the trapped free radicals. (uthor)

Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1963
Accession Number
AD0423525

Entities

People

  • D. Dunbar
  • D. Hale
  • L. A. Harrah
  • R. E. Rondeau
  • S. Zakanycz

Tags

DTIC Thesaurus Topics

  • Acetonitrile
  • Electron Spin Resonance
  • Free Radicals
  • Gamma Rays
  • Gas Chromatography
  • Mass Spectrometry
  • Materials
  • Nitriles
  • Resonance
  • Solid Phases
  • Spectra
  • Spectrometers
  • Spectrometry
  • Spin Resonance

Fields of Study

  • Chemistry

Readers

  • Nuclear and Radiation Engineering.
  • Organic Chemistry
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.

Technology Areas

  • AI & ML
  • AI & ML - Bayesian Inference
  • Microelectronics