INHIBITION OF FLAME REACTIONS.

Abstract

The study of flame inhibition by dispersed solid particles was made in a constant flow system. Solid particles act both by a cooling effect and by a more specific surface destruction of the free radicals which propagate the chain reaction. A theoretical formula is proposed which allows the calculation of the necessary amount of powder which extinguishes the flame. Very good agreement with the experimental data was observed. Homogeneous inhibition by means of additives was investigated and more expecially the behaviour of ternary mixtures (two fuels and one oxidizer of the reverse) at the flammability limits. The reciprocal influence of additives on the flammability limits is to be ascribed both to a temperature effect and to a more specific effect on the reaction kinetics; the substitution of more by less reactive chain carriers (free radicals) takes place. (Author)

Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1963
Accession Number
AD0423667

Entities

People

  • A. Van Tiggelen

Organizations

  • UCLouvain

Tags

DTIC Thesaurus Topics

  • Additives (Chemicals)
  • Agreements
  • Chain Reactions
  • Chemical Kinetics
  • Chemical Reactions
  • Experimental Data
  • Flames
  • Flammability
  • Free Radicals
  • Inhibition
  • Kinetics
  • Particles

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Quantum Chemistry
  • Rocket Propulsion.