ELECTROCHEMISTRY OF FUEL CELL ELECTRODES. SURFACE OXIDATION OF GOLD ELECTRODES

Abstract

The surface oxides formed on electropolished gold by potentiostatic anodization in the range 1.2 1.8 v vs. H(+)/H2 in the same solution, were studied by galvanostatic reduction at current densities between 10 and 1000 microamperes/sq cm. Molar perchlorate solutions of pH 0.04 to 2.1 were employed. The extent of oxide formation is determined by the potential of anodization, the charge increasing linearly with the potential of formation in the range of 1.4 to 1.8 v. Cathodic chronopotentiograms show that reduction of the oxide occurs at a definite potential which depends on the cathodic current density. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1963
Accession Number
AD0423991

Entities

People

  • A. C. Makrides
  • S. B. Brummer

Tags

Communities of Interest

  • Advanced Electronics
  • Weapons Technologies

DTIC Thesaurus Topics

  • Cells
  • Chemical Compounds
  • Chemical Elements
  • Chemistry
  • Current Density
  • Decomposition
  • Electrochemical Reactions
  • Electrochemistry
  • Electrodes
  • Films
  • Materials
  • Materials Science
  • Measurement
  • Military Research
  • New York
  • Photoelectrochemical Cells
  • Standards

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  • Electrochemical Engineering/ Fuel Cell Technologies

Technology Areas

  • Biotechnology