RESEARCH ON PROCEDURES FOR THE LOW-TEMPERATURE PRESERVATION OF BLOOD. THE ANALYTICAL DETERMINATION OF POLYVINYLPYRROLIDONE,

Abstract

Two methods have been developed for the analytical determination of PVP in serum and urine from experimental dogs. In the iodine titration method, the sample is treated with an iodine solution to form a PVP-I2 complex which is spearated from the solution by centifugation, and then disolved in methyl cellosolve. The iodine is titrated with standard thiosulfate solution. In the second method, the absorption of infrared radiation by PVP is measured at a wavelength of 7.75 microns. The iodine method gives values for PVP concentrations in serum and urine which are accurate within = 10%, and the infrared method gives similar accuracy for PVP in serum. In the case of urine samples analyzed by the infrared method, creatinine is sometimes administered to the experimental dogs along with PVP. When the creatinine/PVP weight ratio is less than about 1/1, the accuracy of the PVP determinations by the infrared method is within about = 10%, but when the creatinine/PVP ratio exceeds about 1/1, the accuracy varies from = 10% to = 50% as the creatinine/PVP ratio varies from about 1 to about 100. (Author)

Document Details

Document Type
Technical Report
Publication Date
Dec 13, 1963
Accession Number
AD0425883

Entities

People

  • A. P. Rinfret

Tags

DTIC Thesaurus Topics

  • Absorption
  • Accuracy
  • Creatinine
  • Electromagnetic Radiation
  • Infrared Radiation
  • Ionizing Radiation
  • Low Temperature
  • Optical Phenomena
  • Radiation
  • Standards
  • Titration
  • Urine

Fields of Study

  • Chemistry

Readers

  • Analytical Chemistry