A STATISTICAL INTERPRETATION OF THERMODYNAMICS OF IRREVERSIBLE PROCESSES IN DILUTE GASES,

Abstract

A simplified theory is proposed which fulfills the following requirement: the Boltzmann equation is not solved, even approximately, but used only to supply the minimum information required to compute the transport coefficients. This work is a systematic development originally planned as a thorough investigation of mixtures of polyatomic gases under the so-called dilute gas approximation, with inclusion of chemical kinetics, as well as an investigation of a variety of macroscopic descriptions for mixtures, of which, however, only the two extremes are studied. The report is entirely self-consistent and is intended to be accessible to beginners, prerequisite being only a knowledge of the derivation from first principles of the Boltzmann equation, and elementary properties of the socalled collision operator. All the details are worked out, even the reduction of the so-called curly brackets to ordinary collision integrals, an analysis that is thoroughly carried out by Chapman and Cowling, but which may be much simplified under the present conditions. (Author)

Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1963
Accession Number
AD0426078

Entities

People

  • Jean-pierre Guiraud

Organizations

  • Stanford University

Tags

DTIC Thesaurus Topics

  • Boltzmann Equation
  • Chemical Kinetics
  • Coefficients
  • Collisions
  • Equations
  • Equations Of State
  • Inclusions
  • Integrals
  • Irreversible Processes
  • Kinetics
  • Mathematics
  • Physics
  • Thermodynamics
  • Transport Ships

Readers

  • Calculus or Mathematical Analysis
  • Molecular Photonics/Laser Physics
  • Systems Analysis and Design