CORRELATION OF PHOSPHORUS DISPLACEMENTS.

Abstract

In summary it may be stated that for correlations of rate data in hydroxylic media the doublescale equations of Edwards give excellent results for displacements on most substrates. The n (nucleophilic constant) values of Swain and Scott are good only for displacement on tetrahedral carbon again in essentially hydroxylic media. The rates of nucleophiles which are subject to the alpha effect do not follow even the polarizability basicity scale of Edwards in majority of the cases. (Author)

Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1963
Accession Number
AD0427107

Entities

Organizations

  • Brown University

Tags

DTIC Thesaurus Topics

  • Displacement
  • Elements
  • Equations
  • Group 15 Elements
  • Phosphorus
  • Substrates

Readers

  • Mathematics or Statistics
  • Quantum Chemistry
  • Structural Dynamics.