STUDIES IN ION SOLVATION IN MIXED SOLVENTS.
Abstract
Using the appropriate chemical cells, the free energies to transfer of the pairs of ions H(+)Br (-) and H(+)I(-) in the standard state have been determined for transfers from water to 20% mixtures of dioxan and water at 25 degrees. A byproduct of the measurements is the dissociation constant of boric acid in the mixed solvent. Considerable experimental difficulties have been encountered and overcome in these measurements. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Nov 30, 1963
- Accession Number
- AD0430478
Entities
People
- D. Feakins
Organizations
- Birkbeck, University of London