EFFECT OF THE INTERNAL FIELD ON VIRBRATIONAL BAND SHAPES AND INTENSITIES IN LIQUIDS,

Abstract

An analysis is given of the effect of the frequency dependence of the internal field upon band shapes and intensities in infrared and Raman spectra of liquids. It is shown that band shape in the Raman case is independent of the form of an isotropic internal field, and therefore a reflection of molecular interaction alone, whereas both effects are operative in generating infrared band shapes. Numerical calculations of infrared band shapes in liquids are presented for the Lorentz and Buckingham internal field functions. (Author)

Document Details

Document Type
Technical Report
Publication Date
Jan 15, 1964
Accession Number
AD0431713

Entities

People

  • Karl H. Illinger

Organizations

  • Tufts University

Tags

DTIC Thesaurus Topics

  • Diffraction
  • Electromagnetic Spectra
  • Frequency
  • Intensity
  • Raman Spectra
  • Reflection
  • Spectra

Fields of Study

  • Physics

Readers

  • Materials Science and Engineering.
  • Plasma Physics / Magnetohydrodynamics