RESEARCH ON NEW OXIDANTS AND MECHANISMS OF OXIDANTS.

Abstract

Reactions of ClO3F with a number of selected organic compounds were studied. The following compounds were not attacked by ClO3F: pyridine, tributyl phosphate, methyl benzilate, dimethyl methylphosphonate, and O,O,S - triethyl phosphorothiolate. Piperidine reacted to form the unstable, explosive N-perchloryl piperidine, the first known member of a new class of organic compounds. N-perchloryl piperidine slowly hydrolyzes in base to isotripiperideine-N-oxide. Dimethyl sulfide reacts violently with ClO3F but the reaction can be controlled by the use of solvents or of low gas flow rates of ClO3F. O,O-Diethyl phosphorodithiolate reacts with ClO3F to form at least two condensed species: an oil and crystals. Triethylene diamine reacts with ClO3F to form an unstable, hygroscopic complex of the type N(C2H4)3NClO3(+)F(-). In contrast triethylamine undergoes an exothermic reaction with ClO3F. (Author)

Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1963
Accession Number
AD0431871

Entities

People

  • D. M. Gardner

Tags

DTIC Thesaurus Topics

  • 1-Ring Heterocyclic Compounds
  • Chemical Compounds
  • Contrast
  • Exothermic Reactions
  • Explosives
  • Flow
  • Flow Rate
  • Gas Flow
  • Methylphosphonates
  • Organic Compounds
  • Perchloryl Compounds
  • Pyridines

Fields of Study

  • Chemistry

Readers

  • Analytical Chemistry
  • Marine Propulsion Engineering and Naval Architecture
  • Quantum Chemistry