THE EFFECT OF DISLOCATIONS AND ORIENTATION UPON THE ELECTRICAL DOUBLE LAYER CAPACITY OF SILVER SURFACES. PART I. SUPPLEMENT TO FINAL REPORT OF MARCH 1, 1963: THE EFFECT OF SURFACE PREPARATION AND DISLOCATIONS ON THE SILVER CATALYZED DECOMPOSITION OF FORMIC ACID. PART II.

Abstract

In order to gain more insight into the effects of dislocations and crystal orientation on the catalytic action of metals this research was conducted to determine the effect of dislocation density and crystal orientation on a microscopic area of silver. The results of an experimental investigation to determine the effect of dislocations on catalytic activity are presented. The dislocation density, superficial surface area, hydrogen overpotential area, and mass of a silver catalyst were measured, and the (211) plane of the metal was subsequently used to catalyze the decomposition of formic acid. Although surface preparation of the catalyst was found to have a significant effect on the rate of decomposition, variation in dislocation densities had no observable effect. (Author)

Document Details

Document Type
Technical Report
Publication Date
Apr 01, 1964
Accession Number
AD0434716

Entities

People

  • C. M. Sliepcevich
  • R. D. Daniels
  • R. G. Rein

Organizations

  • University of Oklahoma

Tags

Communities of Interest

  • Air Platforms

DTIC Thesaurus Topics

  • Catalysts
  • Decomposition
  • Dislocations
  • Formic Acid
  • Hydrogen
  • Orientation (Direction)

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Materials Science and Engineering.