THE EFFECTS OF INTERMOLECULAR FORCES ON THE RHEOLOGY OF POLYMERS I: EFFECTS BELOW THE GLASS TEMPERATURE,

Abstract

Two series of styrene copolymers were prepared, containing, respectively, acidic and basic comonomers. The mechanical properties of these copolymers were determined for several temperatures below T sub g. Stoichiometric mixtures of these acidic and basic copolymers were studied over the same temperature range, and their mechanical properties compared to those of the parent materials. It was found that the stoichiometric mixtures showed increased modulus, tensile strength and relaxation times. The increases can be related to functional group content and temperature through simple equations. (Author)

Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1964
Accession Number
AD0437336

Entities

People

  • Edward P. Otocka
  • Frederick R. Eirich

Organizations

  • New York University Tandon School of Engineering

Tags

DTIC Thesaurus Topics

  • Advanced Materials
  • Biomedical And Dental Materials
  • Copolymers
  • Equations
  • Films
  • Materials
  • Mechanical Properties
  • Physical Properties
  • Polymers
  • Relaxation Time
  • Rheology
  • Specialty Uses Of Chemicals
  • Tensile Strength

Fields of Study

  • Materials science

Readers

  • Polymer Science and Technology

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene