CAPTURE COEFFICIENTS OF GASES AT 77 K,

Abstract

The capture coefficients for thirteen common gases at 77K cryosurface temperatures are presented. Several parameters were employed for correlating these capture coefficients. It was found that generally the capture coefficient decreased with decreasing molecular weight, decreasing heat of condensation, and increasing Debye characteristic temperature. Hydrogen bonding in a molecule tended to increase the capture coefficient beyond the expected value. Two empirical parameters one involving surface area of the molecule and the square root of the molecular weight, and the other involving surface energy of the molecule and the inverse square root of the molecular weight appear to give the satisfactory correlation for capture coefficients. (Author)

Document Details

Document Type
Technical Report
Publication Date
May 01, 1964
Accession Number
AD0438484

Entities

People

  • E. S. J. Wang
  • R. F. Brown

Organizations

  • Arnold Engineering Development Complex

Tags

DTIC Thesaurus Topics

  • Coefficients
  • Condensation
  • Energy
  • Heat Energy
  • Hydrogen
  • Molecular Weight
  • Molecules
  • Square Roots
  • Surface Energy
  • Transition Temperature

Fields of Study

  • Chemistry

Readers

  • Calculus or Mathematical Analysis
  • Combustion and Flow Dynamics.
  • Quantum Chemistry